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11.
Generation of Oxazolidine‐2,4‐diones Bearing Sulfur‐Substituted Quaternary Carbon Atoms by Oxothiolation/Cyclization of Ynamides 下载免费PDF全文
Hai Huang Junzhen Fan Dr. Guangke He Zhimin Yang Xiaodong Jin Qi Liu Prof. Dr. Hongjun Zhu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(7):2532-2538
A novel method for metal‐free oxothiolation of ynamides to construct oxazolidine‐2,4‐diones bearing sulfur‐substituted quaternary carbon atoms has been developed. It represents a rare C?O bond cleavage of ynamides, as well as a facile and tandem approach for the formation of C?O, C?S, and C?Cl bonds. This redox‐neutral protocol can be applied to the synthesis of multisubstituted oxazolidine‐2,4‐diones with good chemoselectivity and good yields of isolated products under mild conditions. 相似文献
12.
Back Cover: Ultrasound‐Driven Secondary Self‐Assembly of Amphiphilic β‐Cyclodextrin Dimers (Chem. Eur. J. 13/2015) 下载免费PDF全文
13.
Gold‐Catalyzed Tandem Cycloisomerization–Halogenation of Chiral Homopropargyl Sulfonamides 下载免费PDF全文
Chao Shu Long Li Cang‐Hai Shen Peng‐Peng Ruan Chao‐Yue Liu Prof. Dr. Long‐Wu Ye 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(7):2282-2290
Two new gold‐catalyzed tandem cycloisomerization–halogenation reactions of chiral homopropargyl sulfonamides have been developed. Various enantioenriched 3,3‐diiodopyrrolidin‐2‐ols and 3‐fluoropyrrolidin‐2‐ols were obtained in moderate‐to‐good yields with excellent enantio‐ and diastereoselectivity. 相似文献
14.
Redox‐responsive core cross‐linked micelles of poly(ethylene oxide)‐b‐poly(furfuryl methacrylate) by Diels‐Alder reaction for doxorubicin release 下载免费PDF全文
Cuong M. Q. Le Hai Ha Pham Thi Xuan Thang Cao Gun‐Do Kim Chul‐Woong Oh Kwon Taek Lim 《Journal of polymer science. Part A, Polymer chemistry》2016,54(23):3741-3750
Redox‐responsive core cross‐linked (CCL) micelles of poly(ethylene oxide)‐b‐poly(furfuryl methacrylate) (PEO‐b‐PFMA) block copolymers were prepared by the Diels‐Alder click‐type reaction. First, the PEO‐b‐PFMA amphiphilic block copolymer was synthesized by the reversible addition‐fragmentation chain transfer polymerization. The hydrophobic blocks of PFMA were employed to encapsulate the doxorubicin (DOX) drug, and they were cross‐linked using dithiobismaleimidoethane at 60 °C without any catalyst. Under physiological circumstance, the CCL micelles demonstrated the enhanced structural stability of the micelles, whereas dissociation of the micelles took place rapidly through the breaking of disulfide bonds in the cross‐linking linkages under reduction environment. The core‐cross‐linked micelles showed fine spherical distribution with hydrodynamic diameter of 68 ± 2.9 nm. The in vitro drug release profiles presented a slight release of DOX at pH 7.4, while a significant release of DOX was observed at pH 5.0 in the presence of 1,4‐dithiothreitol. MTT assays demonstrated that the block copolymer did not have any practically cytotoxicity against the normal HEK293 cell line while DOX‐loaded CCL micelles exhibited a high antitumor activity towards HepG2 cells. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3741–3750 相似文献
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Temperature memory effect and its stability revealed via differential scanning calorimetry in ethylene‐vinyl acetate within glass transition range 下载免费PDF全文
Tao Xi Wang Wei Min Huang Hongmei Chen Rui Xiao Hai Bo Lu Shu Feng Kang 《Journal of Polymer Science.Polymer Physics》2016,54(17):1731-1737
In this article, we reveal the temperature memory effect (TME) in a commercial thermoplastic polymer, namely ethylene‐vinyl acetate (EVA), within its glass transition range via a series of differential scanning calorimeter (DSC) tests. In addition, we investigate the influence of heating holding time and also compare the observed TME in current study with that of shape memory alloys (SMAs). It is concluded that the TME via DSC (without any macroscopic shape change) is achievable within the glass transition range of a polymer. Conversely, although the observed TME shares the many similar features as those in SMAs, due to the nature of micro‐Brownian motion in the glass transition of polymers, the resulted TME is strongly affected by the heating holding time. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1731–1737 相似文献
17.
High‐Nuclear Organometallic Copper(I)–Alkynide Clusters: Thermochromic Near‐Infrared Luminescence and Solution Stability 下载免费PDF全文
Hong‐Yan Zhuo Dr. Hai‐Feng Su Zhao‐Zhen Cao Wei Liu Prof. Shu‐Ao Wang Lei Feng Dr. Gui‐Lin Zhuang Dr. Shui‐Chao Lin Prof. Mohamedally Kurmoo Prof. Chen‐Ho Tung Dr. Di Sun Prof. Lan‐Sun Zheng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(49):17619-17626
Cu(CF3COO)2 reacts with tert‐butylacetylene (tBuC≡CH) in methanol in the presence of metallic copper powder to give two air‐stable clusters, [CuI15(tBuC≡C)10(CF3COO)5]?tBuC≡CH ( 1 ) and [CuI16(tBuC≡C)12(CF3COO)4(CH3OH)2] ( 2 ). The assembly process involves in situ comproportionation reaction between Cu2+ and Cu0 and the formation of two different clusters is controlled by reactants concentration. The clusters consist of Cu15 and Cu16 cores co‐stabilized by strong by σ‐ and π‐bonded tert‐butylethynide and CF3COO? (together with methanol molecule in 2 ). Their stabilities in solution were confirmed using electrospray ionization mass spectrometry in which the cluster core remains intact for 1 in chloroform and acetone, and for 2 in acetonitrile. Strong thermochromic luminescence in the near infrared (NIR) region was observed in the solid‐state. Of particular interest, the emission maximum of 1 is red‐shifted from 710 nm at 298 K to 793 nm at 93 K, along with a 17‐fold fluorescence enhancement. In contrast, 2 exhibits red shift from 298 to 123 K followed by blue shift from 123 to 93 K. The emission wavelength was correlated with the structural parameters using variable‐temperature X‐ray single‐crystal analyses. The rich cuprophilic interaction plays a significant role in the formation of 3LMCT (tBuC≡C→Cux) excited state mixed with cluster‐centered (3CC) characters, which can be considerably influenced by temperature, leading to thermochromic luminescence. The present work provides 1) a new synthetic protocol for the high‐nuclear CuI–alkynyl clusters; 2) a comprehensive insight into the mechanism of thermochromic luminescence; 3) unusual emissive materials with the characters of NIR and thermochromic luminescence simultaneously. 相似文献
18.
Lijuan Shen Li Li Sheng Lu Xiaohan Zhang Jie Liu Junlin An Guojun Zhang Bo Wu Fei Wang 《中国颗粒学报》2015,(3):10-15
We conducted measurements of black carbon(BC) aerosol in Jiaxing,China during autumn from September 26 to November 30,2013.We investigated temporal and diurnal variations of BC,and its correlations with meteorological parameters and other major pollutants.Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3,with an average of 5.1 μg/m3.The diurnai variation of BC exhibited a bimodal distribution,with peaks at 07:00 and 18:00.The morning peak was larger than the evening peak.The mass percentages of BC in PM2.5 and PM10 were 7.1%and 4.8%,respectively.The absorption coefficient of BC was calculated to be 44.4 Mm-1,which accounted for 11.1%of the total aerosol extinction.BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11 μg/m3 during the measurement period.Correlation analysis indicated that the main sources of BC were motor vehicle exhaust,and domestic and industrial combustion. 相似文献
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在理论上通过推导得出了Black-Litterman模型(B-L模型)最优权重与信心水平的关系式.实证部分开创性地将多元时间序列VEC模型运用到B-L模型的观点收益预测中.结果表明:且通过向量误差修正模型,实证取得了较好的效果.在任意一种做空限制下,随着信心水平在0%~70%水平上升,收益率有连续上升的趋势,并逐渐趋稳;风险有并不明显的下降的趋势.对同一信心水平而言,随做空限制的放宽,收益率有上升趋势. 相似文献